Here is the stackexchange article:
http://math.stackexchange.com/questi...ed-in-that-way See Adam Hughes response to the question. This is where the mod 4 criteria is helpful. There is nothing about quadratic residues in the answer that I see.
However, reading this again I now picked up on the idea of "integral closure" which might be another key to understanding this better. Here is a definition of an "integral element":
https://en.wikipedia.org/wiki/Integral_element As I see it at the moment, using this term, the reason why Z[√-3] is not the way to get to the ring of integers of the algebraic number field Q(√-3) is because Z[√-3] is not integrally closed in Q(√-3). It needs more integral elements from Q(√-3).
I don't understand this either, but that it seems to make sense makes it worth trying to understand better.