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My personal favorite is the scene in The Good, The Bad, and The Ugly where Tuco meets his brother.
https://www.youtube.com/watch?v=wEDNuuCoZYk
I made a list, trying to think of the best scenes that weren't just car chases, shootouts, or endings and here's what I got.
1.Apocalypse Now- Ride of the Valkyrees
http://www.youtube.com/watch?v=GKaYOW9zMoY
2.Deer Hunter- Russian Roulette
https://www.youtube.com/watch?v=kE_zqVPr4HI
3.Network- I'm as mad as ...