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Chapter 6

TRACHYTE AND BASALT.--DISTRIBUTION OF VOLCANIC ISLES.


The sinking of crystals in fluid lava.
Specific gravity of the constituent parts of trachyte and of basalt, and
their consequent separation.
Obsidian.
Apparent non-separation of the elements of plutonic rocks.
Origin of trap-dikes in the plutonic series.
Distribution of volcanic islands; their prevalence in the great oceans.
They are generally arranged in lines.
The central volcanoes of Von Buch doubtful.
Volcanic islands bordering continents.
Antiquity of volcanic islands, and their elevation in mass.
Eruptions on parallel lines of fissure within the same geological period.



ON THE SEPARATION OF THE CONSTITUENT MINERALS OF LAVA, ACCORDING TO THEIR SPECIFIC GRAVITIES.

One side of Fresh-water Bay, in James Island, is formed by the wreck of a large crater, mentioned in the last chapter, of which the interior has been filled up by a pool of basalt, about two hundred feet in thickness. This basalt is of a grey colour, and contains many crystals of glassy albite, which become much more numerous in the lower, scoriaceous part. This is contrary to what might have been expected, for if the crystals had been originally disseminated in equal numbers, the greater intumescence of this lower scoriaceous part would have made them appear fewer in number. Von Buch has described a stream of obsidian on the Peak of Teneriffe, in which the crystals of feldspar become more and more numerous, as the depth or thickness increases, so that near the lower surface of the stream the lava even resembles a primary rock. ("Description des Isles Canaries" pages 190 and 191.) Von Buch further states, that M. Dree, in his experiments in melting lava, found that the crystals of feldspar always tended to precipitate themselves to the bottom of the crucible. In these cases, I presume there can be no doubt that the crystals sink from their weight. (In a mass of molten iron, it is found ("Edinburgh New Philosophical Journal" volume 24 page 66) that the substances, which have a closer affinity for oxygen than iron has, rise from the interior of the mass to the surface. But a similar cause can hardly apply to the separation of the crystals of these lava-streams. The cooling of the surface of lava seems, in some cases, to have affected its composition; for Dufrenoy ("Mem. pour servir" tome 4 page 271) found that the interior parts of a stream near Naples contained two-thirds of a mineral which was acted on by acids, whilst the surface consisted chiefly of a mineral unattackable by acids.) The specific gravity of feldspar varies from 2.4 to 2.58, whilst obsidian seems commonly to be from 2.3 to 2.4; and in a fluidified state its specific gravity would probably be less, which would facilitate the sinking of the crystals of feldspar. (I have taken the specific gravities of the simple minerals from Von Kobell, one of the latest and best authorities, and of the rocks from various authorities. Obsidian, according to Phillips, is 2.35; and Jameson says it never exceeds 2.4; but a specimen from Ascension, weighed by myself, was 2.42.) At James Island, the crystals of albite, though no doubt of less weight than the grey basalt, in the parts where compact, might easily be of greater specific gravity than the scoriaceous mass, formed of melted lava and bubbles of heated gas.

The sinking of crystals through a viscid substance like molten rock, as is unequivocally shown to have been the case in the experiments of M. Dree, is worthy of further consideration, as throwing light on the separation of the trachytic and basaltic series of lavas. Mr. P. Scrope has speculated on this subject; but he does not seem to have been aware of any positive facts, such as those above given; and he has overlooked one very necessary element, as it appears to me, in the phenomenon--namely, the existence of either the lighter or heavier mineral in globules or in crystals. In a substance of imperfect fluidity, like molten rock, it is hardly credible, that the separate, infinitely small atoms, whether of feldspar, augite, or of any other mineral, would have power from their slightly different gravities to overcome the friction caused by their movement; but if the atoms of any one of these minerals became, whilst the others remained fluid, united into crystals or granules, it is easy to perceive that from the lessened friction, their sinking or floating power would be greatly increased. On the other hand, if all the minerals became granulated at the same time, it is scarcely possible, from their mutual resistance, that any separation could take place. A valuable, practical discovery, illustrating the effect of the granulation of one element in a fluid mass, in aiding its separation, has lately been made: when lead containing a small proportion of silver, is constantly stirred whilst cooling, it becomes granulated, and the grains of imperfect crystals of nearly pure lead sink to the bottom, leaving a residue of melted metal much richer in silver; whereas if the mixture be left undisturbed, although kept fluid for a length of time, the two metals show no signs of separating. (A full and interesting account of this discovery, by Mr. Pattinson, was read before the British Association in September 1838. In some alloys, according to Turner "Chemistry" page 210, the heaviest metal sinks, and it appears that this takes place whilst both metals are fluid. Where there is a considerable difference in gravity, as between iron and the slag formed during the fusion of the ore, we need not be surprised at the atoms separating, without either substance being granulated.) The sole use of the stirring seems to be, the formation of detached granules. The specific gravity of silver is 10.4, and of lead 11.35: the granulated lead, which sinks, is never absolutely pure, and the residual fluid metal contains, when richest, only 1/119 part of silver. As the difference in specific gravity, caused by the different proportions of the two metals, is so exceedingly small, the separation is probably aided in a great degree by the difference in gravity between the lead, when granular though still hot, and when fluid.

In a body of liquified volcanic rock, left for some time without any violent disturbance, we might expect, in accordance with the above facts, that if one of the constituent minerals became aggregated into crystals or granules, or had been enveloped in this state from some previously existing mass, such crystals or granules would rise or sink, according to their specific gravity. Now we have plain evidence of crystals being embedded in many lavas, whilst the paste or basis has continued fluid. I need only refer, as instances, to the several, great, pseudo-porphyritic streams at the Galapagos Islands, and to the trachytic streams in many parts of the world, in which we find crystals of feldspar bent and broken by the movement of the surrounding, semi-fluid matter. Lavas are chiefly composed of three varieties of feldspar, varying in specific gravity from 2.4 to 2.74; of hornblende and augite, varying from 3.0 to 3.4; of olivine, varying from 3.3 to 3.4; and lastly, of oxides of iron, with specific gravities from 4.8 to 5.2. Hence crystals of feldspar, enveloped in a mass of liquified, but not highly vesicular lava, would tend to rise to the upper parts; and crystals or granules of the other minerals, thus enveloped, would tend to sink. We ought not, however, to expect any perfect degree of separation in such viscid materials. Trachyte, which consists chiefly of feldspar, with some hornblende and oxide of iron, has a specific gravity of about 2.45; whilst basalt, composed chiefly of augite and feldspar, often with much iron and olivine, has a gravity of about 3.0. (Trachyte from Java was found by Von Buch to be 2.47; from Auvergne, by De la Beche, it was 2.42; from Ascension, by myself, it was 2.42. Jameson and other authors give to basalt a specific gravity of 3.0; but specimens from Auvergne were found, by De la Beche, to be only 2.78; and from the Giant's Causeway, to be 2.91.) Accordingly we find, that where both trachytic and basaltic streams have proceeded from the same orifice, the trachytic streams have generally been first erupted owing, as we must suppose, to the molten lava of this series having accumulated in the upper parts of the volcanic focus. This order of eruption has been observed by Beudant, Scrope, and by other authors; three instances, also, have been given in this volume. As the later eruptions, however, from most volcanic mountains, burst through their basal parts, owing to the increased height and weight of the internal column of molten rock, we see why, in most cases, only the lower flanks of the central, trachytic masses, are enveloped by basaltic streams. The separation of the ingredients of a mass of lava, would, perhaps, sometimes take place within the body of a volcanic mountain, if lofty and of great dimensions, instead of within the underground focus; in which case, trachytic streams might be poured forth, almost contemporaneously, or at short recurrent intervals, from its summit, and basaltic streams from its base: this seems to have taken place at Teneriffe. (Consult Von Buch's well-known and admirable "Description Physique" of this island, which might serve as a model of descriptive geology.) I need only further remark, that from violent disturbances the separation of the two series, even under otherwise favourable conditions, would naturally often be prevented, and likewise their usual order of eruption be inverted. From the high degree of fluidity of most basaltic lavas, these perhaps, alone, would in many cases reach the surface.

As we have seen that crystals of feldspar, in the instance described by Von Buch, sink in obsidian, in accordance with their known greater specific gravity, we might expect to find in every trachytic district, where obsidian has flowed as lava, that it had proceeded from the upper or highest orifices. This, according to Von Buch, holds good in a remarkable manner both at the Lipari Islands and on the Peak of Teneriffe; at this latter place obsidian has never flowed from a less height than 9,200 feet. Obsidian, also, appears to have been erupted from the loftiest peaks of the Peruvian Cordillera. I will only further observe, that the specific gravity of quartz varies from 2.6 to 2.8; and therefore, that when present in a volcanic focus, it would not tend to sink with the basaltic bases; and this, perhaps, explains the frequent presence, and the abundance of this mineral, in the lavas of the trachytic series, as observed in previous parts of this volume.

An objection to the foregoing theory will, perhaps, be drawn from the plutonic rocks not being separated into two evidently distinct series, of different specific gravities; although, like the volcanic, they have been liquified. In answer, it may first be remarked, that we have no evidence of the atoms of any one of the constituent minerals in the plutonic series having been aggregated, whilst the others remained fluid, which we have endeavoured to show is an almost necessary condition of their separation; on the contrary, the crystals have generally impressed each other with their forms. (The crystalline paste of phonolite is frequently penetrated by long needles of hornblende; from which it appears that the hornblende, though the more fusible mineral, has crystallised before, or at the same time with a more refractory substance. Phonolite, as far as my observations serve, in every instance appears to be an injected rock, like those of the plutonic series; hence probably, like these latter, it has generally been cooled without repeated and violent disturbances. Those geologists who have doubted whether granite could have been formed by igneous liquefaction, because minerals of different degrees of fusibility impress each other with their forms, could not have been aware of the fact of crystallised hornblende penetrating phonolite, a rock undoubtedly of igneous origin. The viscidity, which it is now known, that both feldspar and quartz retain at a temperature much below their points of fusion, easily explains their mutual impressment. Consult on this subject Mr. Horner's paper on Bonn "Geolog. Transact." volume 4 page 439; and "L'Institut" with respect to quartz 1839 page 161.)

In the second place, the perfect tranquillity, under which it is probable that the plutonic masses, buried at profound depths, have cooled, would, most likely, be highly unfavourable to the separation of their constituent minerals; for, if the attractive force, which during the progressive cooling draws together the molecules of the different minerals, has power sufficient to keep them together, the friction between such half-formed crystals or pasty globules would effectually prevent the heavier ones from sinking, or the lighter ones from rising. On the other hand, a small amount of disturbance, which would probably occur in most volcanic foci, and which we have seen does not prevent the separation of granules of lead from a mixture of molten lead and silver, or crystals of feldspar from streams of lava, by breaking and dissolving the less perfectly formed globules, would permit the more perfect and therefore unbroken crystals, to sink or rise, according to their specific gravity.

Although in plutonic rocks two distinct species, corresponding to the trachytic and basaltic series, do not exist, I much suspect that a certain amount of separation of their constituent parts has often taken place. I suspect this from having observed how frequently dikes of greenstone and basalt intersect widely extended formations of granite and the allied metamorphic rocks. I have never examined a district in an extensive granitic region without discovering dikes; I may instance the numerous trap-dikes, in several districts of Brazil, Chile, and Australia, and at the Cape of Good Hope: many dikes likewise occur in the great granitic tracts of India, in the north of Europe, and in other countries. Whence, then, has the greenstone and basalt, forming these dikes, come? Are we to suppose, like some of the elder geologists, that a zone of trap is uniformly spread out beneath the granitic series, which composes, as far as we know, the foundations of the earth's crust? Is it not more probable, that these dikes have been formed by fissures penetrating into partially cooled rocks of the granitic and metamorphic series, and by their more fluid parts, consisting chiefly of hornblende, oozing out, and being sucked into such fissures? At Bahia, in Brazil, in a district composed of gneiss and primitive greenstone, I saw many dikes, of a dark augitic (for one crystal certainly was of this mineral) or hornblendic rock, which, as several appearances clearly proved, either had been formed before the surrounding mass had become solid, or had together with it been afterwards thoroughly softened. (Portions of these dikes have been broken off, and are now surrounded by the primary rocks, with their laminae conformably winding round them. Dr. Hubbard also ("Silliman's Journal" volume 34 page 119), has described an interlacement of trap-veins in the granite of the White Mountains, which he thinks must have been formed when both rocks were soft.) On both sides of one of these dikes, the gneiss was penetrated, to the distance of several yards, by numerous, curvilinear threads or streaks of dark matter, which resembled in form clouds of the class called cirrhi- comae; some few of these threads could be traced to their junction with the dike. When examining them, I doubted whether such hair-like and curvilinear veins could have been injected, and I now suspect, that instead of having been injected from the dike, they were its feeders. If the foregoing views of the origin of trap-dikes in widely extended granitic regions far from rocks of any other formation, be admitted as probable, we may further admit, in the case of a great body of plutonic rock, being impelled by repeated movements into the axis of a mountain-chain, that its more liquid constituent parts might drain into deep and unseen abysses; afterwards, perhaps, to be brought to the surface under the form, either of injected masses of greenstone and augitic porphyry, or of basaltic eruptions. (Mr. Phillips "Lardner's Encyclop." volume 2 page 115 quotes Von Buch's statement, that augitic porphyry ranges parallel to, and is found constantly at the base of, great chains of mountains. Humboldt, also, has remarked the frequent occurrence of trap-rock, in a similar position; of which fact I have observed many examples at the foot of the Chilian Cordillera. The existence of granite in the axes of great mountain chains is always probable, and I am tempted to suppose, that the laterally injected masses of augitic porphyry and of trap, bear nearly the same relation to the granitic axes which basaltic lavas bear to the central trachytic masses, round the flanks of which they have so frequently been erupted.) Much of the difficulty which geologists have experienced when they have compared the composition of volcanic with plutonic formations, will, I think, be removed, if we may believe that most plutonic masses have been, to a certain extent, drained of those comparatively weighty and easily liquified elements, which compose the trappean and basaltic series of rocks.



ON THE DISTRIBUTION OF VOLCANIC ISLANDS.

During my investigations on coral-reefs, I had occasion to consult the works of many voyagers, and I was invariably struck with the fact, that with rare exceptions, the innumerable islands scattered throughout the Pacific, Indian, and Atlantic Oceans, were composed either of volcanic, or of modern coral-rocks. It would be tedious to give a long catalogue of all the volcanic islands; but the exceptions which I have found are easily enumerated: in the Atlantic, we have St. Paul's Rock, described in this volume, and the Falkland Islands, composed of quartz and clay-slate; but these latter islands are of considerable size, and lie not very far from the South American coast (Judging from Forster's imperfect observation, perhaps Georgia is not volcanic. Dr. Allan is my informant with regard to the Seychelles. I do not know of what formation Rodriguez, in the Indian Ocean, is composed.): in the Indian Ocean, the Seychelles (situated in a line prolonged from Madagascar) consist of granite and quartz: in the Pacific Ocean, New Caledonia, an island of large size, belongs (as far as is known) to the primary class. New Zealand, which contains much volcanic rock and some active volcanoes, from its size cannot be classed with the small islands, which we are now considering. The presence of a small quantity of non-volcanic rock, as of clay-slate on three of the Azores (This is stated on the authority of Count V. de Bedemar, with respect to Flores and Graciosa (Charlsworth "Magazine of Nat. Hist." volume 1 page 557). St. Maria has no volcanic rock, according to Captain Boyd (Von Buch "Descript." page 365). Chatham Island has been described by Dr. Dieffenbach in the "Geographical Journal" 1841 page 201. As yet we have received only imperfect notices on Kerguelen Land, from the Antarctic Expedition.), or of tertiary limestone at Madeira, or of clay-slate at Chatham Island in the Pacific, or of lignite at Kerguelen Land, ought not to exclude such islands or archipelagoes, if formed chiefly of erupted matter, from the volcanic class.

The composition of the numerous islands scattered through the great oceans being with such rare exceptions volcanic, is evidently an extension of that law, and the effect of those same causes, whether chemical or mechanical, from which it results, that a vast majority of the volcanoes now in action stand either as islands in the sea, or near its shores. This fact of the ocean-islands being so generally volcanic is also interesting in relation to the nature of the mountain-chains on our continents, which are comparatively seldom volcanic; and yet we are led to suppose that where our continents now stand an ocean once extended. Do volcanic eruptions, we may ask, reach the surface more readily through fissures formed during the first stages of the conversion of the bed of the ocean into a tract of land?

Looking at the charts of the numerous volcanic archipelagoes, we see that the islands are generally arranged either in single, double, or triple rows, in lines which are frequently curved in a slight degree. (Professors William and Henry Darwin Rogers have lately insisted much, in a memoir read before the American Association, on the regularly curved lines of elevation in parts of the Appalachian range.) Each separate island is either rounded, or more generally elongated in the same direction with the group in which it stands, but sometimes transversely to it. Some of the groups which are not much elongated present little symmetry in their forms; M. Virlet ("Bulletin de la Soc. Geolog." tome 3 page 110.) states that this is the case with the Grecian Archipelago: in such groups I suspect (for I am aware how easy it is to deceive oneself on these points), that the vents are generally arranged on one line, or on a set of short parallel lines, intersecting at nearly right angles another line, or set of lines. The Galapagos Archipelago offers an example of this structure, for most of the islands and the chief orifices on the largest island are so grouped as to fall on a set of lines ranging about N.W. by N., and on another set ranging about W.S.W.: in the Canary Archipelago we have a simpler structure of the same kind: in the Cape de Verde group, which appears to be the least symmetrical of any oceanic volcanic archipelago, a N.W. and S.E. line formed by several islands, if prolonged, would intersect at right angles a curved line, on which the remaining islands are placed.

Von Buch ("Description des Isles Canaries" page 324.) has classed all volcanoes under two heads, namely, CENTRAL VOLCANOES, round which numerous eruptions have taken place on all sides, in a manner almost regular, and VOLCANIC CHAINS. In the examples given of the first class, as far as position is concerned, I can see no grounds for their being called "central;" and the evidence of any difference in mineralogical nature between CENTRAL VOLCANOES and VOLCANIC CHAINS appears slight. No doubt some one island in most small volcanic archipelagoes is apt to be considerably higher than the others; and in a similar manner, whatever the cause may be, that on the same island one vent is generally higher than all the others. Von Buch does not include in his class of volcanic chains small archipelagoes, in which the islands are admitted by him, as at the Azores, to be arranged in lines; but when viewing on a map of the world how perfect a series exists from a few volcanic islands placed in a row to a train of linear archipelagoes following each other in a straight line, and so on to a great wall like the Cordillera of America, it is difficult to believe that there exists any essential difference between short and long volcanic chains. Von Buch (Idem page 393.) states that his volcanic chains surmount, or are closely connected with, mountain-ranges of primary formation: but if trains of linear archipelagoes are, in the course of time, by the long- continued action of the elevatory and volcanic forces, converted into mountain-ranges, it would naturally result that the inferior primary rocks would often be uplifted and brought into view.

Some authors have remarked that volcanic islands occur scattered, though at very unequal distances, along the shores of the great continents, as if in some measure connected with them. In the case of Juan Fernandez, situated 330 miles from the coast of Chile, there was undoubtedly a connection between the volcanic forces acting under this island and under the continent, as was shown during the earthquake of 1835. The islands, moreover, of some of the small volcanic groups which thus border continents, are placed in lines, related to those along which the adjoining shores of the continents trend; I may instance the lines of intersection at the Galapagos, and at the Cape de Verde Archipelagoes, and the best marked line of the Canary Islands. If these facts be not merely accidental, we see that many scattered volcanic islands and small groups are related not only by proximity, but in the direction of the fissures of eruption to the neighbouring continents--a relation, which Von Buch considers, characteristic of his great volcanic chains.

In volcanic archipelagoes, the orifices are seldom in activity on more than one island at a time; and the greater eruptions usually recur only after long intervals. Observing the number of craters, that are usually found on each island of a group, and the vast amount of matter which has been erupted from them, one is led to attribute a high antiquity even to those groups, which appear, like the Galapagos, to be of comparatively recent origin. This conclusion accords with the prodigious amount of degradation, by the slow action of the sea, which their originally sloping coasts must have suffered, when they are worn back, as is so often the case, into grand precipices. We ought not, however, to suppose, in hardly any instance, that the whole body of matter, forming a volcanic island, has been erupted at the level, on which it now stands: the number of dikes, which seem invariably to intersect the interior parts of every volcano, show, on the principles explained by M. Elie de Beaumont, that the whole mass has been uplifted and fissured. A connection, moreover, between volcanic eruptions and contemporaneous elevations in mass has, I think, been shown to exist in my work on Coral-Reefs, both from the frequent presence of upraised organic remains, and from the structure of the accompanying coral-reefs. (A similar conclusion is forced on us, by the phenomena, which accompanied the earthquake of 1835, at Concepcion, and which are detailed in my paper (volume 5 page 601) in the "Geological Transactions.") Finally, I may remark, that in the same Archipelago, eruptions have taken place within the historical period on more than one of the parallel lines of fissure: thus, at the Galapagos Archipelago, eruptions have taken place from a vent on Narborough Island, and from one on Albemarle Island, which vents do not fall on the same line; at the Canary Islands, eruptions have taken place in Teneriffe and Lanzarote; and at the Azores, on the three parallel lines of Pico, St. Jorge, and Terceira. Believing that a mountain-axis differs essentially from a volcano, only in plutonic rocks having been injected, instead of volcanic matter having been ejected, this appears to me an interesting circumstance; for we may infer from it as probable, that in the elevation of a mountain-chain, two or more of the parallel lines forming it may be upraised and injected within the same geological period.


Charles Darwin

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